Mercury intrusion porosimetry

In mercury intrusion porosimetry the non-wetting properties of mercury are used to gain information on the porous characteristics of solid materials. A higher pressure is needed to force intrusion of mercury in smaller pores. In this way a wide dynamic range of pores can be measured starting from 4 nm (pressure = 400 MPa) up to 200 µm (vacuum). As a consequence, this technique is extremely suitable for materials showing broad distributions of pores or mainly macropores. Prior to the analysis, vacuum degassing is used to remove moisture from the porous structure.

The low and high-pressure intrusion measurements are performed on the CE Instruments Pascal 140 and 440, respectively. The report comprises a graphical representation of the intrusion and extrusion curve and the corresponding pore size distribution accompanied by data on pore volume and porosity.